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微軟雅黑, "Microsoft YaHei"; font-size: 14px;">怎么知道活性炭的吸附性質？</span></p><p style="text-indent: 2em;"><span style="font-family: 微軟雅黑, "Microsoft YaHei"; font-size: 14px;">吸附性質是活性炭的首要性質?；钚蕴烤哂邢袷Яs無規則地排列的微晶。在活化進程中微晶間發生了形狀不同、巨細不一的孔隙，假定活性炭的孔隙是圓筒孔形狀，按必定辦法核算孔隙的半徑巨細可分為二類：</span></p><p style="text-indent: 2em;"><span style="font-family: 微軟雅黑, "Microsoft YaHei"; font-size: 14px;">(1) 按IUPAC分：</span></p><p style="text-indent: 2em;"><span style="font-family: 微軟雅黑, "Microsoft YaHei"; font-size: 14px;">微孔 <1.0nm</span></p><p style="text-indent: 2em;"><span style="font-family: 微軟雅黑, "Microsoft YaHei"; font-size: 14px;">中孔 1-25nm</span></p><p style="text-indent: 2em;"><span style="font-family: 微軟雅黑, "Microsoft YaHei"; font-size: 14px;">大孔 >25nm。</span></p><p style="text-indent: 2em;"><span style="font-family: 微軟雅黑, "Microsoft YaHei"; font-size: 14px;">(2) 按習慣分：</span></p><p style="text-indent: 2em;"><span style="font-family: 微軟雅黑, "Microsoft YaHei"; font-size: 14px;">微孔 <150nm</span></p><p style="text-indent: 2em;"><span style="font-family: 微軟雅黑, "Microsoft YaHei"; font-size: 14px;">中孔 150-20 000nm</span></p><p style="text-indent: 2em;"><span style="font-family: 微軟雅黑, "Microsoft YaHei"; font-size: 14px;">大孔 >20 000nm。</span></p><p style="text-indent: 2em;"><span style="font-family: 微軟雅黑, "Microsoft YaHei"; font-size: 14px;">因為這些孔隙，特別是微孔提供了巨大的外表積。</span></p><p style="text-indent: 2em;"><span style="font-family: 微軟雅黑, "Microsoft YaHei"; font-size: 14px;">微孔的孔隙容積一般只要0.25-0.9mL/g，孔隙數量約為1020個/g,悉數微孔外表積約為500-1500m2/g，一般以BET法測算，也有稱高達3500-5000 m2/g的?；钚蕴亢喼?5%以上的外表積都在微孔中，因而除了有些大分子進不了外，微孔是決定活性炭吸附功用凹凸的重要因素。中孔的孔隙容積一般約為0.02-1.0mL/g，外表積最高可達幾百平方米，一般只要活性炭總蠶種的約5%。其作用能吸附蒸汽，并能為吸附物提供進入微孔的通道，又能直接吸附較大的分子。</span></p><p style="text-align: center; text-indent: 0em;"><span style="font-family: 微軟雅黑, "Microsoft YaHei"; font-size: 14px;"><img src="/data/upload/image/20190328/1553738530265167.png" title="1553738530265167.png" alt="6.png"/></span></p><p style="text-indent: 2em;"><span style="font-family: 微軟雅黑, "Microsoft YaHei"; font-size: 14px;">大孔的孔隙容積一般約為0.2-0.5 mL/g，外表積只約0.5-2 m2/g，其作用一是使吸附質分子快速深化活性炭內部較小的孔隙中去；二是作為催化載體時，催化劑常少數沉淀在微孔內，大都沉淀在大孔和中孔之中。</span></p><p style="text-indent: 2em;"><span style="font-family: 微軟雅黑, "Microsoft YaHei"; font-size: 14px;">所提的活性炭外表積理應包含內外表積和外外表積，事實上吸附性質首要來自巨大的內外表積，因而不能誤認為：把活性炭研碎磨細會明顯提高外表積然后提高吸附力。</span></p><p style="text-indent: 2em;"><span style="font-family: 微軟雅黑, "Microsoft YaHei"; font-size: 14px;">許多吸附是可逆的物理吸附，即被吸附物為流體，在必定溫度和壓力下被活性炭吸附，在高溫低壓下被吸附物又解吸出來，活性炭內外表康復原狀。這是廣泛運用的物理吸附，學術上又稱為范德華吸附。</span></p><p style="text-indent: 2em;"><span style="font-family: 微軟雅黑, "Microsoft YaHei"; font-size: 14px;">化學性</span></p><p style="text-indent: 2em;"><span style="font-family: 微軟雅黑, "Microsoft YaHei"; font-size: 14px;">活性炭的吸附除了物理吸附，還有化學吸附?；钚蕴康奈叫约热Q于孔隙結構，又取決于化學組成。</span></p><p style="text-indent: 2em;"><span style="font-family: 微軟雅黑, "Microsoft YaHei"; font-size: 14px;">活性炭不只含碳，并且含少數的化學結合、功用團開工的氧和氫，例如羰基、羧基、酚類、內酯類、醌類、醚類。這些外表上含有的氧化物和絡合物，有些來自質料的衍生物，有些是在活化時、活化后由空氣或水蒸氣的作用而生成。有時還會生成外表硫化物和氯化物。在活化中質料所含礦物質會集到活性炭里成為灰分，灰分的首要成分是堿金屬和堿土金屬的鹽類，如碳酸鹽和磷酸鹽等。</span></p><p style="text-indent: 2em;"><span style="font-family: 微軟雅黑, "Microsoft YaHei"; font-size: 14px;">這些灰分含量可經水洗或酸洗的處理而下降。</span></p><p style="text-indent: 2em;"><span style="font-family: 微軟雅黑, "Microsoft YaHei"; font-size: 14px;">活性炭中無機物成分，從表3-1四種粉炭商品的剖析，可見一斑。</span></p><p style="text-indent: 2em;"><span style="font-family: 微軟雅黑, "Microsoft YaHei"; font-size: 14px;">催化性</span></p><p style="text-indent: 2em;"><span style="font-family: 微軟雅黑, "Microsoft YaHei"; font-size: 14px;">活性炭在許多吸附進程中伴有催化聽憑，表現出催化劑的活性。例如活性炭吸附二氧化硫經催化氧化變成三氧化硫。</span></p><p style="text-indent: 2em;"><span style="font-family: 微軟雅黑, "Microsoft YaHei"; font-size: 14px;">因為活性炭有特異的外表含氧化合物或絡合物的存在，對多種反響具有催化劑的活性，例如使氯氣和一氧化碳生成光氣。</span></p><p style="text-indent: 2em;"><span style="font-family: 微軟雅黑, "Microsoft YaHei"; font-size: 14px;">因為活性炭和載持物之間會構成絡合物，這種絡合物催化劑使催化活性大增，例如載持鈀鹽的活性炭，即便沒有銅鹽的催化劑存在，烯烴的氧化反響也能催化進行，并且速度快、挑選性高。</span></p><p style="text-indent: 2em;"><span style="font-family: 微軟雅黑, "Microsoft YaHei"; font-size: 14px;">因為活性炭具有興旺的細孔結構、巨大的內外表積和很好的耐熱性、耐酸性、耐堿性，可作為催化劑的載體。例如，有機化學中加氫、脫氫環化、異構化等的反響中，活性炭是鉑、鈀催化劑的優秀載體。</span></p><p style="text-indent: 2em;"><span style="font-family: 微軟雅黑, "Microsoft YaHei"; font-size: 14px;">機械性</span></p><p style="text-indent: 2em;"><span style="font-family: 微軟雅黑, "Microsoft YaHei"; font-size: 14px;">下載幾個項目標明活性炭的機械性，為活性炭的運用者，尤其為許多的工業運用者所注重。</span></p><p style="text-indent: 2em;"><span style="font-family: 微軟雅黑, "Microsoft YaHei"; font-size: 14px;">(1) 粒度：選用一套規范篩篩分法，求出留在和通過每只篩子的活性炭分量，標明粒度散布。</span></p><p style="text-indent: 2em;"><span style="font-family: 微軟雅黑, "Microsoft YaHei"; font-size: 14px;">(2) 靜觀密度或堆密度：飲食孔隙容積和顆粒間空隙容積的單位體積活性炭的分量。</span></p><p style="text-indent: 2em;"><span style="font-family: 微軟雅黑, "Microsoft YaHei"; font-size: 14px;">(3) 體積密度和顆粒密度：飲食孔隙容積而不飲食顆粒間空隙容積的單位體積活性炭的分量。</span></p><p style="text-indent: 2em;"><span style="font-family: 微軟雅黑, "Microsoft YaHei"; font-size: 14px;">(4) 強度：即活性炭的耐破碎性。</span></p><p style="text-indent: 2em;"><span style="font-family: 微軟雅黑, "Microsoft YaHei"; font-size: 14px;">(5) 耐磨性：即耐磨損或抗磨擦的功用。</span></p><p style="text-indent: 2em;"><span style="font-family: 微軟雅黑, "Microsoft YaHei"; font-size: 14px;">這些機械性質直接影響運用，例如：密度影響容器巨細；粉炭粗細影響過濾；粒炭粒度散布影響流體阻力和壓降；破碎性影響運用壽命和廢炭再生。</span></p></div> <h3 class="tag">本文網址：http://www.pulp-friction.com/news/379.html </h3> <h3 class="tag">關鍵詞：<a href="http://www.pulp-friction.com/tag/%E6%B4%BB%E6%80%A7%E7%82%AD%E5%8E%82%E5%AE%B6">活性炭廠家</a>,<a href="http://www.pulp-friction.com/tag/%E4%BA%91%E5%8D%97%E6%B4%BB%E6%80%A7%E7%82%AD">云南活性炭</a>,<a href="http://www.pulp-friction.com/tag/%E6%A4%B0%E5%A3%B3%E6%B4%BB%E6%80%A7%E7%82%AD%E5%8E%82%E5%AE%B6">椰殼活性炭廠家</a> </h3> <div class="page">上一篇：<a href="http://www.pulp-friction.com/news/378.html">活性炭吸附法在水處理中的運用有哪些？</a><br 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